论文标题

镀铬液晶的弹性四分之一扭曲理论

An Elastic Quartic Twist Theory for Chromonic Liquid Crystals

论文作者

Paparini, Silvia, Virga, Epifanio G.

论文摘要

染色性液晶是溶晶材料,它对它们对生物系统的适应性引起了人们的兴趣。为了描述它们的弹性特性,经典的Oseen-Frank理论需要异常的小扭曲常数和(相对)的大型鞍形播放常数,以至于违反了Ericksen的一种不平等,这可以保证Oseen-Frank储存的能量 - 能量密度在下面界定。尽管这种违规并不能阻止固定几何限制问题中平衡扭曲的存在和稳定性,但对液滴的自由边缘问题的研究表明,有许多矛盾的后果。通过采用富含不同扭曲的扭曲的针状触觉来构建推动总能量到负无穷大的序列的最小化序列[PHY。 Rev. E 106,044703(2022)]。为了克服这些困难,我们在这里提出了一种新型的弹性理论,该理论扩展了传播经典的Oseen-Frank储存能量,通过添加四重奏扭曲项。我们表明,液滴的总能量在四分之一的扭曲理论中是有限的,因此排除了已知的悖论。四分之一的术语在理论中引入了现象学长度$ a $;这会影响限制在毛细管内的染色体的平衡。使用已发布的实验数据使我们能够估计$ a $。

Chromonic liquid crystals are lyotropic materials which are attracting growing interest for their adapatbility to living systems. To describe their elastic properties, the classical Oseen-Frank theory requires anomalously small twist constants and (comparatively) large saddle-splay constants, so large as to violate one of Ericksen's inequalities, which guarantee that the Oseen-Frank stored-energy density is bounded below. While such a violation does not prevent the existence and stability of equilibrium distortions in problems with fixed geometric confinement, the study of free-boundary problems for droplets has revealed a number of paradoxical consequences. Minimizing sequences driving the total energy to negative infinity have been constructed by employing ever growing needle-shaped tactoids incorporating a diverging twist [Phy. Rev. E 106, 044703 (2022)]. To overcome these difficulties, we propose here a novel elastic theory that extends for chromonics the classical Oseen-Frank stored energy by adding a quartic twist term. We show that the total energy of droplets is bounded below in the quartic twist theory, so that the known paradoxes are ruled out. The quartic term introduces a phenomenological length $a$ in the theory; this affects the equilibrium of chromonics confined within capillary tubes. Use of published experimental data allows us to estimate $a$.

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