论文标题

Angulon的变分理论及其旋转光谱学

Variational theory of angulons and their rotational spectroscopy

论文作者

Zeng, Zhongda, Yakaboylu, Enderalp, Lemeshko, Mikhail, Shi, Tao, Schmidt, Richard

论文摘要

Angulon是由量子转子形成的Quasiparticle,由多体浴的激发装扮形成,可用于描述在液体或固体环境中旋转的杂质。在这里,我们在共旋转框架中提出了一个连贯的状态ansatz,该框架提供了对Angulon的全面理论描述。我们揭示了准颗粒的性能,例如能量,准粒子的重量和光谱函数,并表明我们的Ansatz由于多体敷料而导致杂质旋转常数持续下降,这与实验性观察一致。从我们的研究中,Angulon的图片是一种有效的自旋与磁场相互作用,该磁场是由分子旋转自谐产生的。此外,我们讨论了旋转光谱,该光谱的重点是旋转分子对线性响应方案中激光扰动的响应。重要的是,我们考虑了先前研究中已忽略的初始状态相互作用,并揭示了它们对激发光谱的影响。为了检查Angulon的不稳定性制度,我们使用单启示ANSATZ并获得与实验一致的结果,在该结果中,由于初始状态相互作用,观察到光谱线的扩大,而声子机翼仍被高度抑制。

The angulon, a quasiparticle formed by a quantum rotor dressed by the excitations of a many-body bath, can be used to describe an impurity rotating in a fluid or solid environment. Here we propose a coherent state ansatz in the co-rotating frame which provides a comprehensive theoretical description of angulons. We reveal the quasiparticle properties, such as energies, quasiparticle weights and spectral functions, and show that our ansatz yields a persistent decrease in the impurity's rotational constant due to many-body dressing, consistent with experimental observations. From our study, a picture of the angulon emerges as an effective spin interacting with a magnetic field that is self-consistently generated by the molecule's rotation. Moreover, we discuss rotational spectroscopy, which focuses on the response of rotating molecules to a laser perturbation in the linear response regime. Importantly, we take into account initial-state interactions that have been neglected in prior studies and reveal their impact on the excitation spectrum. To examine the angulon instability regime, we use a single-excitation ansatz and obtain results consistent with experiments, in which a broadening of spectral lines is observed while phonon wings remain highly suppressed due to initial-state interactions.

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