论文标题
cr $ _ {1+x} $ pt $ _ {5-x} $ p的高温铁磁性
High Temperature Ferromagnetism in Cr$_{1+x}$Pt$_{5-x}$P
论文作者
论文摘要
我们介绍Cr $ _ {1+X} $ PT $ _ {5-X} $ P的增长和基本磁性和传输属性。我们表明,单晶可以很容易地从通过在基于PT-P的熔体中添加稀释量Cr产生的高温溶液生长。像其他1-5-1化合物一样,Cr $ _ {1+X} $ PT $ _ {5-X} $ P采用四方P4/mmm结构组成的面部共享CRPT $ _3 $,例如P Assheets sheets沿C-axis沿C轴破坏的板。 EDS和X射线衍射测量都表明Cr $ _ {1+X} $ PT $ _ {5-X} $ P之间的Cr和Pt原子之间的占用混合,类似于与密切相关的化合物CRPT $ _3 $中发现的,CR $ _ {1.5} $ pt $ _5}的真实组成我们报告说,Cr $ _ {1.5} $ PT $ _ {4.5} $ P订购在T $ _c $ = 464.5 k时以$ \ $ \ $ 2.1 $ \ $ 2.1 $μ__ {\ textit {b textIt {b}} $/cr的饱和度与强量相关的COUPT,$ 2.1 $ \ $ \ 2.1 $ \ 2.1 $ \ $ 2.1 $ \ 2.1 $ \ $ \。 cr $ _ {1.5} $ pt $ _ {4.5} $ P具有异常强的平面各向异性,估计的各向异性字段分别为345 KOE和220 KOE,分别为1.8 K和300 K。 Cr $ _ {1.5} $ pt $ _ {4.5} $ P的电阻具有金属温度依赖性,磁性相对较弱。电子带结构的计算表明,CRPT $ _5 $ P在费米水平附近的状态密度中具有很大的峰值,该状态被分为旋转多数,在铁磁状态下。此外,计算表明,在费米水平附近CR-3D和PT-5D状态之间进行了实质性杂交,与实验测量的各向异性一致。
We present the growth and basic magnetic and transport properties of Cr$_{1+x}$Pt$_{5-x}$P. We show that single crystals can readily be grown from a high-temperature solution created by adding dilute quantities of Cr to Pt-P based melts. Like other 1-5-1 compounds, Cr$_{1+x}$Pt$_{5-x}$P adopts a tetragonal P4/mmm structure composed face-sharing CrPt$_3$ like slabs that are broken up along the c-axis by sheets of P atoms. EDS and X-ray diffraction measurements both suggest Cr$_{1+x}$Pt$_{5-x}$P has mixed occupancy between Cr and Pt atoms, similar to what is found in the closely related compound CrPt$_3$, giving real compositions of Cr$_{1.5}$Pt$_{4.5}$P (x = 0.5). We report that Cr$_{1.5}$Pt$_{4.5}$P orders ferromagnetically at T$_C$ = 464.5 K with a saturated moment of $\approx$ 2.1 $μ_{\textit{B}}$/Cr at 1.8 K. Likely owing to the strong spin-orbit coupling associated with the large quantity of high Z Pt atoms, Cr$_{1.5}$Pt$_{4.5}$P has exceptionally strong planar anisotropy with estimated anisotropy fields of 345 kOe and 220 kOe at 1.8 K and 300 K respectively. The resistance of Cr$_{1.5}$Pt$_{4.5}$P has a metallic temperature dependence with relatively weak magnetoresistance. Electronic band structure calculations show that CrPt$_5$P has a large peak in the density of states near the Fermi level which is split into spin majority and minority bands in the ferromagnetic state. Furthermore, the calculations suggest substantial hybridization between Cr-3d and Pt-5d states near the Fermi level, in agreement with the experimentally measured anisotropy.