论文标题

表面附近的非高斯扩散

Non-Gaussian diffusion near surfaces

论文作者

Alexandre, Arthur, Lavaud, Maxime, Fares, Nicolas, Millan, Elodie, Louyer, Yann, Salez, Thomas, Amarouchene, Yacine, Guérin, Thomas, Dean, David S.

论文摘要

我们研究了被限制在单个壁附近的颗粒的扩散,在双壁平面通道几何形状中,局部扩散率取决于到边界的距离。平行于墙壁的位移的特征是布朗尼人,但它的非高斯具有非零四分之一累积的特征。建立与泰勒色散的联系,我们计算了一般扩散张量张量的第四个累积剂和位移分布的尾部以及壁或外部产生的电势,例如重力。 胶体在平行于壁的方向上运动的实验和数值研究给出了测得的第四个累积物,这是我们理论正确预测的。有趣的是,与布朗迄今 - 非高斯扩散的模型相反,位移分布的尾巴被证明是高斯,而不是指数。总而言之,我们的结果提供了其他测试和限制,以推断力图和表面附近的局部运输特性的推断。

We study the diffusion of particles confined close to a single wall and in double-wall planar channel geometries where the local diffusivities depend on the distance to the boundaries. Displacement parallel to the walls is Brownian as characterized by its variance, but it is non-Gaussian having a non-zero fourth cumulant. Establishing a link with Taylor dispersion, we calculate the fourth cumulant and the tails of the displacement distribution for general diffusivity tensors along with potentials generated by either the walls or externally, for instance gravity. Experimental and numerical studies of the motion of a colloid in the direction parallel to the wall give measured fourth cumulants which are correctly predicted by our theory. Interestingly, contrary to models of Brownian-yet-non-Gaussian diffusion, the tails of the displacement distribution are shown to be Gaussian rather than exponential. All together, our results provide additional tests and constraints for the inference of force maps and local transport properties near surfaces.

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