论文标题

最终型横向推动聚合物的新兴构象特性

Emergent conformational properties of end-tailored transversely propelling polymers

论文作者

Prathyusha, K. R., Ziebert, Falko, Golestanian, Ramin

论文摘要

我们研究了单个活性半串联聚合物的动力学和构象,该聚合物的单体经历了垂直于局部切线的推进力,其最终珠与内珠不同(“最终尾巴”)。使用Langevin模拟,我们证明,除了侧向运动外,末端珠和聚合物主链之间的相对推进强度显着改变了聚合物的构象性能,这是弯曲刚度,终止量和推进力的函数。预计,对于较慢的末端,聚合物曲线远离移动方向,而更快的末端则导致相反的弯曲,在这两种情况下,与直纤维相比,略微降低了质量速度的中心。有趣的是,对于更快的末端珠,有一个丰富而动态的形态图:聚合物末端可能会折叠成2D环或发夹样构象,这些构象由于其形状的不对称性和在完全推进过程中相当直的状态周围的不对称性而旋转而旋转。我们使用缩放和运动学论证合理化模拟,并介绍构象的状态图。侧向推进的纤维包括一个相当尚未开发和多才多艺的自我旋转器类别,他们的研究将打开新颖的设计方法,例如柔软机器人技术中的运动驱动器或混合器。

We study the dynamics and conformations of a single active semiflexible polymer whose monomers experience a propulsion force perpendicular to the local tangent, with the end beads being different from the inner beads ("end-tailored"). Using Langevin simulations, we demonstrate that, apart from sideways motion, the relative propulsion strength between the end beads and the polymer backbone significantly changes the conformational properties of the polymers as a function of bending stiffness, end-tailoring and propulsion force. Expectedly, for slower ends the polymer curves away from the moving direction, while faster ends lead to opposite curving, in both cases slightly reducing the center of mass velocity compared to a straight fiber. Interestingly, for faster end beads there is a rich and dynamic morphology diagram: the polymer ends may get folded together to 2D loops or hairpin-like conformations that rotate due to their asymmetry in shape and periodic flapping motion around a rather straight state during full propulsion is also possible. We rationalize the simulations using scaling and kinematic arguments and present the state diagram of the conformations. Sideways propelled fibers comprise a rather unexplored and versatile class of self-propellers, and their study will open novel ways for designing, e.g. motile actuators or mixers in soft robotics.

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