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Unlike conventional anti-eavesdropping methods that always require additional energy or computing resources (e.g., in friendly jamming and cryptography-based solutions), this work proposes a novel anti-eavesdropping solution that comes with mostly no extra power nor computing resource requirement. This is achieved by leveraging the ambient backscatter communications in which secret information can be transmitted by backscattering it over ambient radio signals. Specifically, the original message at the transmitter is first encoded into two parts: (i) active transmit message and (ii) backscatter message. The active transmit message is then transmitted by using the conventional wireless transmission method while the backscatter message is transmitted by backscattering it on the active transmit signals via an ambient backscatter tag. As the backscatter tag does not generate any active RF signals, it is intractable for the eavesdropper to detect the backscatter message. Therefore, secret information, e.g., secret key for decryption, can be carried by the backscattered message, making the adversary unable to decode the original message. Simulation results demonstrate that our proposed solution can significantly enhance security protection for communication systems.