论文标题

电活性聚合物条的弯曲建模

Modeling of the bending of an electroactive polymer strip

论文作者

Tixier, Mireille, Pouget, J

论文摘要

离子电活性聚合物(例如Nafion)可以用作传感器或执行器。为此,将水饱和材料的薄膜夹在两个电极之间。水饱和导致聚合物的准完全分离和小阳离子的释放。电场在厚度中的应用导致条带的弯曲。相反,当条带弯曲时,可以在两个电极之间检测到电压。这种现象涉及电力技术类型的多物理耦合。我们先前已经对该系统进行了建模,并使用线性不可逆过程的热力学确定了其组成型方程。我们将此模型应用于悬臂豌豆条的情况下,在其两个面之间经受了连续的电压(静态情况)。使用大量位移的梁模型计算施加力和尖端位移。我们还研究了要在自由端行使的力以防止其位移(阻塞力)。在Nafion的情况下进行了数量模拟。我们绘制了阳离子浓度,压力,电场和潜力的曲线厚度。这些数量在条带的中心几乎是恒定的,在电极附近差异很大。获得的尖端位移和阻塞力的值与文献中发表的实验数据非常吻合。这两个数量是施加的电势的线性函数。尖端位移随长度平方而变化,并且阻塞力与宽度成正比,并且与长度成反比。

Ionic electro-active polymer (Nafion for example) can be used as sensor or actuator. To this end, a thin film of the water-saturated material is sandwiched between two electrodes. Water saturation causes a quasi-complete dissociation of the polymer and the release of small cations. The application of an electric field across the thickness results in the bending of the strip. Conversely, a voltage can be detected between the two electrodes when the strip is bent. This phenomenon involves multiphysics couplings of electro-mechanical-chemical type. We have previously modeled this system and determined its constitutive equations using the thermodynamics of linear irreversible processes.We applied this model to the case of a cantilevered PEA strip subjected to a continuous voltage between its two faces (static case). The applied forces and the tip displacement are calculated using a beam model in large displacements. We have also studied the force to be exercised on the free end to prevent its displacement (blocking force).Numerical simulations were performed in the case of Nafion. We have drawn the profiles of cations concentration, pressure, electric field and potential in the thickness of the strip. These quantities, which are almost constant in the central part of the strip, vary drastically near the electrodes. The obtained values of the tip displacement and the blocking force are in good agreement with the experimental data published in the literature. These two quantities are linear functions of the imposed electrical potential ; the tip displacement varies as the length square, and the blocking force is proportional to the width and inversely proportional to the length.

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