学术文献库

While phase-change materials (PCMs) composed of chalcogenide have different crystallization mechanisms (CM), such as nucleation-dominated Ge2Sb2Te5 (GST) and growth-dominated GeTe (GT), revealing the essential reason of CM as well as the tuned properties is still a long-standing issue. Here, we remarkably find the distinct stability of Te-terminated (111) boundaries (TTB) in different systems, which provides a path to understand the difference in CM. It stems from the quantum effect of molecular orbital theory: the optimal local chemical composition results in the formation of TTB without dangling bonds (DB) in GST but with DB in GT, where DB destabilizes boundary due to its distorted local environment mismatching Oh symmetry of p orbitals. Moreover, the inner vacancy concentration in GST is alterable and controlled by TTB, manifested by the absence of cubic-to-hexagonal transition in carbon-doped GST of small grains and minimized inner vacancy. Finally, the charge transport property (CTP) is controlled by boundary via changing the density of charge or hole nearby as well as vacancy. These findings open the door to tune CTP by CM, which is necessary for achieving low-power and ultrafast devices.