论文标题

墙附近的胶体哑铃的高度分布和方向

Height Distribution and Orientation of Colloidal Dumbbells Near a Wall

论文作者

Verweij, Ruben W., Ketzetzi, Stefania, de Graaf, Joost, Kraft, Daniela J.

论文摘要

几何限制强烈影响微粒在液体环境中的行为。然而,迄今为止,即使像平面壁一样简单,非球形粒子行为也几乎没有探索。在这里,我们通过数字性全息显微镜测量墙壁上方胶体哑铃的高度分布和方向。我们发现,虽然较大的哑铃几乎平行于墙壁,但同一材料的较小哑铃在优选角度出人意料地定向。我们通过考虑引力效应和静电颗粒壁相互作用来确定作用在哑铃上的总高度依赖性力。我们的建模表明,在特定高度下,哑铃上的净力和扭矩分别在热力和能量下方,这使观察到的方向成为可能。我们的结果突出了非球形颗粒的丰富近壁动力学,并可以进一步有助于开发定量框架,以限制任意形状的微粒动力学。

Geometric confinement strongly influences the behavior of microparticles in liquid environments. However, to date, nonspherical particle behaviors close to confining boundaries, even as simple as planar walls, remain largely unexplored. Here, we measure the height distribution and orientation of colloidal dumbbells above walls by means of digital in-line holographic microscopy. We find that while larger dumbbells are oriented almost parallel to the wall, smaller dumbbells of the same material are surprisingly oriented at preferred angles. We determine the total height-dependent force acting on the dumbbells by considering gravitational effects and electrostatic particle-wall interactions. Our modeling reveals that at specific heights both net forces and torques on the dumbbells are simultaneously below the thermal force and energy, respectively, which makes the observed orientations possible. Our results highlight the rich near-wall dynamics of nonspherical particles, and can further contribute to the development of quantitative frameworks for arbitrarily-shaped microparticle dynamics in confinement.

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