论文标题

硫 - 亚素合金涂料的耐腐蚀性

Corrosion Resistance of Sulfur-Selenium Alloy Coatings

论文作者

Susarla, Sandhya, Chilkoor, Govind, Cui, Yufei, Arif, Taib, Tsafack, Thierry, Puthirath, Anand, Sudeep, Parambath M., Kalimuthu, Jawahar R., Hassan, Aly, Castro-Pardo, Samuel, Barnes, Morgan, Verduzco, Rafael, Filleter, Tobin, Koratkar, Nikhil, Gadhamshetty, Venkataramana, Rahman, Muhammad M, Ajayan, Pulickel M.

论文摘要

尽管进行了数十年的研究,但在许多工程应用中,金属腐蚀仍然是一个长期的挑战。具体而言,设计一种可以在非生物和生物环境中抗腐蚀的材料仍然难以捉摸。在这里,我们设计了具有高刚度和延展性的轻质硫 - 硫酸(S-SE)合金,可以用作钢在各种不同环境中的防护效率约为99.9%的通用耐腐蚀涂层。 S-SE涂层的低碳钢显示出比非生物(模拟海水和硫酸钠溶液)和生物(硫酸盐还原细菌培养基)环境中的裸金属低6-7个数量级。涂层具有很强的粘合剂和机械稳健的作用。我们将合金在各种环境中的高腐蚀性归因于其半晶,非孔,抗微生物和粘弹性性质,具有出色的机械性能,使其能够成功阻止各种扩散物种。

Despite decades of research, metallic corrosion remains a long-standing challenge in many engineering applications. Specifically, designing a material that can resist corrosion both in abiotic as well as biotic environments remains elusive. Here we design a lightweight sulfur-selenium (S-Se) alloy with high stiffness and ductility that can serve as a universal corrosion-resistant coating with protection efficiency of ~99.9% for steel in a wide range of diverse environments. S-Se coated mild steel shows a corrosion rate that is 6-7 orders of magnitude lower than bare metal in abiotic (simulated seawater and sodium sulfate solution) and biotic (sulfate-reducing bacterial medium) environments. The coating is strongly adhesive and mechanically robust. We attribute the high corrosion resistance of the alloy in diverse environments to its semi-crystalline, non-porous, anti-microbial, and viscoelastic nature with superior mechanical performance, enabling it to successfully block a variety of diffusing species.

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