论文标题
二维的两长度尺度核心液体的结构行为
Structural behavior of a two length scale core-softened fluid in two dimensions
论文作者
论文摘要
2D竞争系统显示了各种各样的固体和聚集模式,重点流体相,这是KTHNY理论所预测的连续融化,在某些情况下是水性异常。在本文中,我们对langevin Dynamics模拟进行了类似坡道的核心流体,该模拟具有两个特征长度尺度和上述所有特征。分析该系统的流体相,Bordin和Barbosa [Phys。 Rev. E 97,022604(2018)]报告存在两个水样异常区域。现在,我们重新审视了这个问题,集中在低温方向上,以及较大的密度范围,以寻求异常行为的起源,实心相和重点熔化之间的关系。现在,没有观察到两个,而是三个异常区域。额外的异常区域与无定形固体熔融到簇流体的融化有关。它们不仅由电势中的特征长度尺度之间的竞争来统治,而且还由各种颗粒构象引起的额外竞争所统治。这些竞争从固体延伸到流体相,反映在结构水样异常中。我们的结果使两个长度尺度的竞争潜力的复杂行为有些启发,并有助于阐明这些系统中大量的实心相和存在多个水性异常区域之间的关系。
2D competitive systems shows a large variety of solid and aggregate patterns, re-entrant fluid phase, a continuous melting as predicted by the KTHNY theory and, in some cases, waterlike anomalies. In this paper, we employ Langevin Dynamics simulations of a ramp-like core-softened fluid that have two characteristic length scales and all the features mentioned above. Analyzing the fluid phase of this system, Bordin and Barbosa [Phys. Rev. E 97, 022604 (2018)] reported the existence of two waterlike anomalous region. Now, we revisit this problem focusing in the low temperature regime and a larger range of densities looking for a relation between the origin of the anomalous behavior, the solid phases and the re-entrant melting. Now, not two, but three anomalous regions were observed. The extra anomalous regions are related to the re-entrant melting of a amorphous solid to a cluster fluid. They are ruled not only by the competition between the characteristic length scales in the potential, but also by extra competitions induced by the variety of particles conformations. These competitions extends from the solid to the fluid phase, reflecting in the structural waterlike anomaly. Our results shade some light in the complex behavior of two length scales competitive potential, and helps to elucidate the relation between the large number of solid phases and the existence of more than one waterlike anomalies region in these systems.