论文标题
Ultralong-Range Rydberg双分子
Ultralong-range Rydberg bi-molecules
论文作者
论文摘要
我们预测，在冷和超低环境中极性分子之间的碰撞中，超距离rydberg双分子形成。 $λ$ -DOUBLET NITRIC氧化物（NO）与长寿命的Rydberg No（$ nf $，$ ng $）分子的碰撞形成了具有GHz Energies和Kilo-Debye Enervy Electry Electry Dipole Moments的Ultranong-Range Rydberg bi-Molecules。哈密顿量包括各向异性电荷 - 分子偶极子相互作用和电子不散射。 Rydberg双分子的旋转常数在MHz范围内，可以在Rydberg Bi-Molecules中进行旋转过渡的微波光谱。无法实现无偶极子的相当方向。此处描述的Rydberg分子对一类特殊类型的双分子相互作用的研究有希望。
We predict that ultralong-range Rydberg bi-molecules form in collisions between polar molecules in cold and ultracold settings. The collision of $Λ$-doublet nitric oxide (NO) with long-lived Rydberg NO($nf$, $ng$) molecules forms ultralong-range Rydberg bi-molecules with GHz energies and kilo-Debye permanent electric dipole moments. The Hamiltonian includes both the anisotropic charge-molecular dipole interaction and the electron-NO scattering. The rotational constant for the Rydberg bi-molecules is in the MHz range, allowing for microwave spectroscopy of rotational transitions in Rydberg bi-molecules. Considerable orientation of NO dipole can be achieved. The Rydberg molecules described here hold promise for studies of a special class of long-range bi-molecular interactions.
