论文标题

关于在多晶超合金中退火和蠕变下的硼化物的粗化机理和变形

On the coarsening mechanism and deformation of borides under annealing and creep in a polycrystalline superalloy

论文作者

Lilensten, Lola, Kostka, Aleksander, Lartigue-Korinek, Sylvie, Antonov, Stoichko, Tin, Sammy, Gault, Baptiste, Kontis, Paraskevas

论文摘要

我们已经研究了蠕变后的晶间CRICH M2B硼化物的粗糙机制,并以850°C退火大约3000小时,以多晶镍的超合金为基础。在蠕变后发现硼化物较粗糙,与没有外部施加载荷(400-600nm)的硼化物相比,与硼化物相比,测得的厚度在800-1100nm的范围内。在850℃下暴露之前,硼化物的厚度为100-200nm。透射电子显微镜表明,变形的硼化物具有四方I4/MCM结构,或者具有正交FDDD,而这两个结构则在单个粒子中共存。在粗糙的硼化物中系统地观察到了非常高的平面断层密度。这些断层与B和Cr的化学波动相关,这通过原子探针断层扫描揭示。我们的结果使我们能够暗示通过表外观样机制来硼化物。此外,在蠕变提供了对硼化物变形的见解后,在硼化物内的位错上观察到了Ni和Co的分配。讨论了晶间硼化物对多晶超合金的蠕变性能的后果。

We have investigated the coarsening mechanism of intergranular Cr-rich M2B borides after creep and annealing at 850C for approximately 3000 hours in a polycrystalline nickel-based superalloy. Borides were found to be coarser after creep, with measured thicknesses in the range of 800-1100nm, compared to borides annealed in the absence of external applied load (400-600nm). The borides had a thickness of 100-200nm before exposure at 850C. Transmission electron microscopy revealed that coarsened borides have either the tetragonal I4/mcm structure, or the orthorhombic Fddd, with those two structures coexisting in a single particle. The presence of a very high density of planar faults is systematically observed within the coarsened borides. The faults were correlated with chemical fluctuations of B and Cr, revealed by atom probe tomography. Our results allow us to suggest that borides coarsen by an epitaxy-like mechanism. In addition, partitioning of Ni and Co was observed at dislocations within the borides after creep providing insights into the deformation of borides. Consequences of coarsened intergranular borides on the creep performance of polycrystalline superalloys are discussed.

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