论文标题

NICU双层tio $ _2 $纳米管启用有效的贵金属无金属光催化$ H_2 $ Evolution of tio $ _2

Templated Dewetting-Alloying of NiCu Bilayers on TiO$_2$ Nanotubes Enables Efficient Noble Metal-Free Photocatalytic $H_2$ Evolution

论文作者

Spanu, Davide, Recchia, Sandro, Mohajernia, Shiva, Tomanec, Ondrei, Kment, Stepan, Zboril, Radek, Schmukia, Patrik, Altomare, Marco

论文摘要

光催化$ H_2 $对原始TIO $ _2 $的进化反应的特征是由于电荷载体的捕获和重组而引起的低效率,并且由于电子传输的动力学效率低。高贵金属(主要是PT,PD,AU)纳米颗粒通常在Tio $ _2 $表面上以cocatalyst的形式装饰,以达到合理的光催化产率。但是,由于高贵金属的高成本,正在开发替代金属的催化剂。在这里,我们介绍了一种方法,以基于阳极Tio $ _2 $纳米管阵列的合金NICU cococatalytic纳米粒子来制造$ H_2 $进化的高效贵金属光催化平台。 NICU BiLayers通过等离子体溅射存放在Tio $ _2 $纳米管上。随后进行了导致脱水的热处理,即由于表面扩散,Ni和Cu溅射层同时互相混合,并在纳米管表面分成NICU纳米颗粒。该方法可以完全控制合金纳米颗粒的关键特征,例如其成分,工作功能和cocatalytic能力,以$ h_2 $生成。由等质和铜量组成的脱水合成的卵巢纳米颗粒不仅比纯的Ni或Cu纳米颗粒更具反应性,而且还会导致$ H_2 $的发电率可与传统贵金属(PT)装饰Tio $ _2 $ _2 $ nanotube nanotube Arrays Arays可比性可比性。

Photocatalytic $H_2$ evolution reactions on pristine TiO$_2$ is characterized by low efficiencies due to trapping and recombination of charge carriers, and due to a sluggish kinetics of electron transfer. Noble metal (mainly Pt, Pd, Au) nanoparticles are typically decorated as cocatalyst on the TiO$_2$ surface to reach reasonable photocatalytic yields. However, owing to the high cost of noble metals, alternative metal cocatalysts are being developed. Here we introduce an approach to fabricate an efficient noble metal free photocatalytic platform for $H_2$ evolution based on alloyed NiCu cocatalytic nanoparticles at the surface of anodic TiO$_2$ nanotube arrays. NiCu bilayers are deposited onto the TiO$_2$ nanotubes by plasma sputtering. A subsequent thermal treatment is carried out that leads to dewetting, that is, owing to surface diffusion the Ni and Cu sputtered layers simultaneously mix with each other and split into NiCu nanoparticles at the nanotube surface. The approach allows for a full control over key features of the alloyed nanoparticles such as their composition, work function and cocatalytic ability towards $H_2$ generation. Dewetted-alloyed cocatalytic nanoparticles composed of equal Ni and Cu amounts not only are significantly more reactive than pure Ni or Cu nanoparticles, but also lead to $H_2$ generation rates that can be comparable to those obtained by conventional noble metal (Pt) decoration of TiO$_2$ nanotube arrays.

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