论文标题
识别碳作为六角硼硝化硼的可见单光子发射的来源
Identifying Carbon as the Source of Visible Single Photon Emission from Hexagonal Boron Nitride
论文作者
论文摘要
六角硼(HBN)中的单光子发射器(SPE)在过去几年中由于其出色的光学特性而引起了极大的关注。然而,尽管实验结果和理论计算广泛,但负责观察到的排放的缺陷结构仍然难以捉摸。在这里,通过控制将杂质掺入HBN并比较各种合成方法,我们提供了直接的证据,表明可见的SPE与碳相关。这些缺陷的集合显示了室温光学检测到的磁共振(ODMR)。我们还进行离子植入实验,并确认只有碳植入在可见光谱范围内产生SPE。对数百个潜在的基于碳的缺陷过渡的计算分析表明,发射是由带负电荷的VBCN缺陷引起的,该缺陷经历了远程空间外变形,并且对环境敏感。我们的结果解决了关于HBN可见范围内单个发射器的起源的长期辩论,将是确定量子光子设备这些缺陷的关键。
Single photon emitters (SPEs) in hexagonal boron nitride (hBN) have garnered significant attention over the last few years due to their superior optical properties. However, despite the vast range of experimental results and theoretical calculations, the defect structure responsible for the observed emission has remained elusive. Here, by controlling the incorporation of impurities into hBN and by comparing various synthesis methods, we provide direct evidence that the visible SPEs are carbon related. Room temperature optically detected magnetic resonance (ODMR) is demonstrated on ensembles of these defects. We also perform ion implantation experiments and confirm that only carbon implantation creates SPEs in the visible spectral range. Computational analysis of hundreds of potential carbon-based defect transitions suggest that the emission results from the negatively charged VBCN- defect, which experiences long-range out-of-plane deformations and is environmentally sensitive. Our results resolve a long-standing debate about the origin of single emitters at the visible range in hBN and will be key to deterministic engineering of these defects for quantum photonic devices.